Liquid –Liquid Equilibria of Systems Containingsunflower Oil, Ethanol and Water

Liquid–liquid equilibria for ethyl esters + ethanol + water systems: Experimental measurements and CPA EoS modeling

The knowledge and the capacity to describe the liquid–liquid equilibria of systems composed of fatty acid ethyl esters, ethanol and water are crucial for an adequate design of the biodiesel washing units found in the ethylic biodiesel production processes. Since limited data is available for systems of this kind, in this work measurements were carried out for fatty acid ethyl esters + ethanol +...

Liquid-liquid Equilibrium in Systems Containing Olive Oil, Free Fatty Acids, Ethanol and Water

This paper reports experimental data and the thermodynamic modeling of the liquid-liquid equilibrium systems with triacylglycerols, free fatty acids (obtained from olive oil), ethanol and water. The experimental data were fitted using the UNIQUAC model, in which absolute deviation of 1.28 % and root mean square deviation of 2.10 % between experimental and calculated mass fraction of the compone...

Effect of Magnetic Field on the Liquid-liquid Equilibria of (Water + Acetic Acid + Organic Solvent) Ternary Systems

The effect of magnetic field on the liquid-liquid equilibrium of two ternary systems (water + acetic acid + butyl acetate and water + acetic acid + dimethyl succinate) at 298.15 K under atmospheric pressure was investigated. The results obtained show that the strength of the magnetic field (0.02 T) affects the solubility of acetic acid in the used organic solvents. Distribution coefficients and...

Prediction of Liquid-Liquid Equilibria of Binary Systems Containing Alcohols Using EoS-GE Models

Modeling of liquid–liquid equilibria of aqueous alcohol + salt systems using amodified NRTL

The modified NRTL (m-NRTL) model is used to represent the excess Gibbs free energy of aqueous (alcohol + electrolyte) solutions. In this work, the m-NRTL model previously developed for representation of vapor-liquid equilibria for (polymer + salt + water) systems has been extended to represent liquid-liquid equilibria of (alcohol + salt + water) systems. The proposed extension is a modified of ...